Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2cc37337h | DOI Listing |
Publication Analysis
Top Keywords
nitrosyl isomerism
4
isomerism amorphous
4
amorphous mntppno
4
mntppno solids
4
solids reaction
4
reaction amorphous
4
amorphous mntpp
4
mntpp layers
4
layers mntppno
4
mntppno isomers
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!