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Organophilic worm-like ruthenium nanoparticles catalysts by the modification of CTAB on montmorillonite supports. | LitMetric

Organophilic worm-like ruthenium nanoparticles catalysts by the modification of CTAB on montmorillonite supports.

J Colloid Interface Sci

College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, PR China. Electronic address:

Published: February 2013

A supported Ru catalyst was prepared by using cetyltrimethylammonium bromide (CTAB) intercalated montmorillonite as the supporting matrix. The as-prepared Ru catalyst was subsequently characterized by XRD, XPS, N(2) sorption, TEM, and dispersibility measurement. The results showed that the Ru nanoparticles were in the modified montmorillonite interlayers, and the morphology of Ru nanoparticle was worm-like. Moreover, this supported Ru catalyst could be well dispersed in organic solvents such as toluene. The catalyst exhibited high activity and selectivity in the hydrogenation of quinoline even without stirring.

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http://dx.doi.org/10.1016/j.jcis.2012.10.019DOI Listing

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