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Nuclear inelastic scattering of (57)Fe labeled [NiFe] hydrogenase is shown to give information on different states of the enzyme. It was thus possible to detect and assign Fe-CO and Fe-CN bending and stretching vibrations of the active site outside the spectral range of the Fe-S cluster normal modes.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3535562 | PMC |
| http://dx.doi.org/10.1002/anie.201204616 | DOI Listing |
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