Recent experimental and theoretical work has focused on ferromagnetic nanotubes due to their potential applications as magnetic sensors or as elements in high-density magnetic memory. The possible presence of magnetic vortex states-states which produce no stray fields-makes these structures particularly promising as storage devices. Here we investigate the behavior of the magnetization states in individual Ni nanotubes by sensitive cantilever magnetometry. Magnetometry measurements are carried out in the three major orientations, revealing the presence of different stable magnetic states. The observed behavior is well-described by a model based on the presence of uniform states at high applied magnetic fields and a circumferential onion state at low applied fields.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/nl302950u | DOI Listing |
Adv Sci (Weinh)
January 2025
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India.
Stabilizing large easy-axis type magnetic anisotropy in molecular complexes is a challenging task, yet it is crucial for the development of information storage devices and applications in molecular spintronics. Achieving this requires a deep understanding of electronic structure and the relationships between structure and properties to develop magneto-structural correlations that are currently unexplored in the literature. Herein, a series of five-coordinate distorted square pyramidal Co complexes [Co(L)(X)].
View Article and Find Full Text PDFDalton Trans
December 2024
Center for Integrated Materials Research, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark.
In the study of mononuclear transition metal single molecule magnets (SMMs), extensive research has concentrated on identifying optimal coordination geometries around the central metal ion to enhance SMM properties. However, the role of non-covalent interactions in the second coordination sphere has been relatively underexplored. Here, we study the impact of non-covalent Cl⋯H interactions on the magnetic anisotropy of the central Co(II) ion in the distorted axially compressed octahedral complex CoCl(tu) (1) (tu = SC(NH)).
View Article and Find Full Text PDFNat Commun
September 2024
Department of Physics and Astronomy, Purdue University, West Lafayette, IN, 47907, USA.
Optically addressable spin defects in three-dimensional (3D) crystals and two-dimensional (2D) van der Waals (vdW) materials are revolutionizing nanoscale quantum sensing. Spin defects in one-dimensional (1D) vdW nanotubes will provide unique opportunities due to their small sizes in two dimensions and absence of dangling bonds on side walls. However, optically detected magnetic resonance of localized spin defects in a nanotube has not been observed.
View Article and Find Full Text PDFInorg Chem
September 2024
Department of Chemistry "Ugo Schiff", DICUS and INSTM Research Unit, University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Florence, Italy.
ACS Nano
January 2023
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York14853, United States.
The sensitivity of magnetic resonance force microscopy (MRFM) is limited by surface noise. Coating a thin-film polymer sample with metal has been shown to decrease, by orders of magnitude, sample-related force noise and frequency noise in MRFM experiments. Using both MRFM and inductively detected measurements of electron-spin resonance, we show that thermally evaporating a 12 nm gold layer on a 40 nm nitroxide-doped polystyrene film inactivates the nitroxide spin labels to a depth of 20 nm, making single-spin measurements difficult or impossible.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!