Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal-organic framework.

Chem Commun (Camb)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

Published: December 2012

A μ(4)-Cl bridged anionic sodalite-type porous metal-organic framework (Et(2)NH(2))(3)[(Cu(4)Cl)(3)(TTCA)(8)]·26DEF was synthesized, in which Et(2)NH(2)(+) can be exchanged by Li(+) cations. The results of gas measurements indicate that Et(2)NH(2)(+) and Li(+) are beneficial for methane and hydrogen storage, respectively.

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Source
http://dx.doi.org/10.1039/c2cc35461fDOI Listing

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