AM-6 with high intensity visible light absorption at 400-800 nm was synthesized via a hydrothermal route in the presence of F(-) ions. Structure characterization and DFT calculations indicate that the unusual optical properties originate from the connection of octahedral VO(6) wires with distorted tetrahedral VO(4) units, which are stabilized in the framework of AM-6.
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| http://dx.doi.org/10.1039/c2cc36083g | DOI Listing |
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