AI Article Synopsis
- The compound features two nearly eclipsed cyclo-penta-dienyl (Cp) rings with a very small dihedral angle of 2.54°.
- One Cp ring has a nitro-benzenamine group that is nearly perpendicular to it, with a torsion angle of 89.8°.
- The structure includes intra-molecular N-H⋯O and N-H⋯N hydrogen bonds, along with weak C-H⋯O hydrogen bonds connecting neighboring molecules in the crystal.
Article Abstract
In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2)O(2))], the two cyclo-penta-dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro-benzenamine group, which is essentially perpendicular to the substituted cyclo-penta-dienyl ring, with an N-C(H(2))-C-C torsion angle of 89.8 (2)°. Intra-molecular N-H⋯O and N-H⋯N hydrogen bonds occur. In the crystal, weak C-H⋯O hydrogen bonds link adjacent mol-ecules.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470183 | PMC |
| http://dx.doi.org/10.1107/S1600536812039177 | DOI Listing |
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