In the crystal structure of the title compound, [Ru(3)(C(9)H(11)P)H(2)(C(18)H(15)P)(CO)(8)], the triangular Ru(3) unit is capped with one mesitylphosphin-idene ligand. In the trigonal-pyramidal Ru(3)P core, one Ru(II) atom is coordinated by a triphenyl-phosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru-Ru bonds. These Ru-Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru-Ru bond [2.8146 (4) Å]. The terminal triphenyl-phosphane ligand coordinates to the Ru(II) atom, which is involved in two hydride bridges.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470165 | PMC |
| http://dx.doi.org/10.1107/S1600536812039499 | DOI Listing |
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