The state of dispersion plays an important role on the performance of polymer nanocomposites. Dispersion is usually assessed based on the qualitative evaluation of microscopy micrographs. In this paper, a quantitative algorithm is introduced for analyzing the dispersion of inclusions in polymer composites using image analysis. In a binary image, on-pixels are considered as particle elements while off-pixels stand for matrix elements. To quantify the dispersion, the mean distance value between any matrix elements to their corresponding nearest neighboring particle element is measured. A dispersion index, DI, is then defined by comparing the image of interest with the associated uniformly dispersed case. Synthetic models were utilized to examine the sensitivity of the algorithm to various dispersity scenarios such as the effect of particle size, clustering, and cluster distribution. Optical micrographs of carbon nanotube modified epoxy with different states of dispersion were also employed to assess the applicability and functionality of the algorithm to real micrographs.
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http://dx.doi.org/10.1021/am301459q | DOI Listing |
Int J Biol Macromol
January 2025
Department of Food Science and Technology, Sari Agricultural Science and Natural Resources University, PO BOX 578, Sari, Mazandaran, Iran.
This study aimed to develop bead-free nanofibers for effective omega-3 encapsulation using optimal mixing ratios of whey protein isolate (WPI)/polyvinyl alcohol (PVA) blends via electrospinning method. Various WPI-PVA ratios (100:0, 90:10, 80:20, 70:30, 60:40, 50:50 v/v) were examined for surface tension, viscosity, and conductivity. SEM images revealed uneven nanofibers with bead at 90:10 and 80:20 ratios, while the 70:30 ratio produced uniform and bead-free nanofibers with an average diameter of 262.
View Article and Find Full Text PDFInt J Nanomedicine
January 2025
Department of Drug Sciences, University of Pavia, Pavia, 27100, Italy.
Purpose: The main purpose of the study was the formulation development of nanogels (NHs) composed of chondroitin sulfate (CS) and low molecular weight chitosan (lCH), loaded with a naringenin-β-cyclodextrin complex (NAR/β-CD), as a potential treatment for early-stage diabetic retinopathy.
Methods: Different formulations of NHs were prepared by varying polymer concentration, lCH ratio, and pH and, then, characterized for particle size, zeta potential, particle concentration (particles/mL) and morphology. Cytotoxicity and internalization were assessed in vitro using Human Umbilical Vein Endothelial Cells (HUVEC).
Polymers (Basel)
January 2025
Institute of Textile Auxiliary and Ecological Dyeing Finishing, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, China.
A simple and non-chemical binding nanofiber (-CD/PA) adsorbent was obtained by electrospinning a mixture of -cyclodextrin (-CD) and polyacrylate (PA). The cationic dyes in wastewater were removed by the host-guest inclusion complex of the -cyclodextrin and the electrostatic interaction between the polyacrylate and the dyes groups. The influence of the content of -cyclodextrin on the surface morphology and adsorption capacity of the nanofiber membrane was discussed, and the optimized adsorption capacity of nanofiber adsorption material was determined.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovića 28 a, 10000 Zagreb, Croatia.
This research follows the principles of circular economy through the zero waste concept and cascade approach performed in two steps. Our paper focuses on the first step and explores the characteristics of developed biocomposite materials made from a biodegradable poly(lactic acid) polymer (PLA) reinforced with natural fibers isolated from the second generation of biomass (agricultural biomass and weeds). Two plants, L.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Dental Medicine and Nursing, Faculty of Medicine, Lucian Blaga University of Sibiu, 550169 Sibiu, Romania.
Following implantation, infections, inflammatory reactions, corrosion, mismatches in the elastic modulus, stress shielding and excessive wear are the most frequent reasons for orthopedic implant failure. Natural polymer-based coatings showed especially good results in achieving better cell attachment, growth and tissue-implant integration, and it was found that the inclusions of nanosized fillers in the coating structure improves biomineralization and consequently implant osseointegration, as the nanoparticles represent calcium phosphate nucleation centers and lead to the deposition of highly organized hydroxyapatite crystallites on the implant surface. In this study, magnetic nanoparticles synthesized by the co-precipitation method were used for the preparation of cellulose acetate composite coatings through the phase-inversion method.
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