Soft synthesis of isocyanate-functionalised metal-organic frameworks.

Dalton Trans

Dipartimento di Chimica and NIS Centre of Excellence, Università di Torino, Via Pietro Giuria 7, 10125 Torino, Italia.

Published: December 2012

We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH(2) metal-organic framework into its corresponding isocyanate (-NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.

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Source
http://dx.doi.org/10.1039/c2dt31977bDOI Listing

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