New Au(25) nanoclusters stabilized by heterotopic 4-aminothiophenolate ligands (HSPhNH(2)) have been isolated with a yield of ~70%. The nanoclusters formula determined by ESI-MS is Au(25)(SPhNH(2))(17), with the 18(th) position occupied by an amine or DMF molecules to close their electronic shell.
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| http://dx.doi.org/10.1039/c2nr32367b | DOI Listing |
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