Two 3D heterometal-organic frameworks based on infrequent trigonal bipyramidal Ln(5) clusters as nodes were structurally and magnetically characterized (Ln=Gd (1), Dy (2)). The results indicate large MCE of up to 30.7 J kg(-1) K(-1) in 1 and slow magnetic relaxation behavior in 2. Expectedly, constructing 3D MOFs based on multinuclear clusters as nodes may will be a new strategy for achieving large -ΔS(m). Additionally, compound 1 exhibits high thermal and solvent stabilities, providing a favorable foundation for realistic applications.
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- * Findings reveal that rhomboid and trigonal bipyramid geometries are the most stable for Li and Li clusters, respectively, and the data gathered aids in evaluating the reliability of current electronic structure theories and advancing new computational models.
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