We analyze the increase in precision of parameters estimation for polarization-resolved second-harmonic generation imaging microscopy when two intensities are measured with two orthogonal analyzers. The analysis is performed for measuring anisotropy parameters and molecule orientation for samples with cylindrical symmetry in the presence of photon noise with Poisson statistics. The improvement in comparison to global intensity measurement (i.e., without analyzer) is discussed.
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http://dx.doi.org/10.1364/OL.37.004173 | DOI Listing |
Anal Chem
November 2024
Biological Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99354, United States.
The ability to uniquely identify a compound requires highly precise and orthogonal measurements. Here we describe a newly developed analytical platform that integrates high resolution ion mobility and cryogenic vibrational ion spectroscopy for high-precision structural characterizations. This platform allows for the temporal separation of isomeric/isobaric ions and provides a highly sensitive description of the ion's adopted geometry in the gas phase.
View Article and Find Full Text PDFMass Spectrom Rev
November 2024
Mass Spectrometry Consulting Ltd, City of Bar, Montenegro.
Time-of-flight mass spectrometry (TOF MS) excels in rapid and high-sensitivity analysis, making it a cornerstone of analytical chemistry. But as sample complexity explodes in omics studies, so does the need for higher resolving power to ensure accurate results. Traditional TOF instruments face a challenge: achieving high resolution often requires a very large instrument.
View Article and Find Full Text PDFJ Synchrotron Radiat
November 2024
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 239 Zhangheng Road, Pudong New District, Pudong 201204, People's Republic of China.
Anal Chem
October 2024
Department of Precision Instruments, State Key Laboratory of Precision Measurement Technology and Instruments, Tsinghua University, Beijing 100084, China.
To overcome the light power fluctuation and frequency mismatch in photoacoustic spectroscopy (PAS), we proposed a self-corrected 1-only resonant cell-based PAS (1-RCPAS) gas analyzer. Based on the theoretical analysis of the 1 signal, a signal processing algorithm considering laser power-current nonlinearity is proposed. The 1-only algorithm is well-tailored for the resonant systems, requiring no time-division multiplexing.
View Article and Find Full Text PDFFront Plant Sci
August 2024
College of Electronic Engineering (College of Artificial Intelligence), South China Agricultural University, Guangzhou, China.
This study examines the impact of canopy density, side wind speed, nozzle tilt angle, and droplet size on droplet penetration during plant protection spraying operations. Experiments conducted in citrus orchards evaluated how side wind speed and nozzle tilt angle influence droplet penetration across various canopy densities. A Phase Doppler Analyzer (PDA) was used to assess droplet size variations under different nozzle tilt angles and side wind speeds, yielding a multiple linear regression equation (R = 0.
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