Rare-earth phosphors are commonly used in display panels, security printing, and fluorescent lamps, and have potential applications in lasers and bioimaging. In the present study, Eu3+- and Dy3+-codoped uniform-shaped Y2O3 submicron particles were prepared using the urea homogeneous precipitation method. The structure and morphology of the resulting particles were characterized by X-ray diffraction, field emission scanning electron microscope, and field emission transmission electron microscope, whereas their optical properties were monitored by photoluminescence spectroscopy. The room-temperature luminescence color emission of the synthesized particles can be tuned from red to yellow by switching the excitation wavelength from 254 to 350 nm. The luminescence intensities of red and yellow emissions could be altered by varying the dopant concentration. Strong quenching was observed at high Eu3+ and Dy3+ concentrations in the Y2O3 host lattice.
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http://dx.doi.org/10.1186/1556-276X-7-556 | DOI Listing |
Dalton Trans
January 2025
Yildiz Technical University, Faculty of Chemical and Metallurgical Engineering, Department of Metallurgical and Materials Engineering, Glass Research and Development Laboratory, Istanbul, 34220, Türkiye.
Elevated temperatures can lead to reabsorption and color drift, compromising the quality of phosphor-converted white light-emitting diode (pc-WLED) devices. To ensure the performance of WLEDs under these conditions, it is essential to develop luminescent materials that maintain stable color. Consequently, there is a pressing need for single-phase white-emitting phosphors with robust chromatic stability.
View Article and Find Full Text PDFJ Fluoresc
January 2025
Department of Applied Physics, Delhi Technological University, New Delhi, 110 042, India.
Dy and Eu co-doped borosilicate glasses have been synthesised via melt quench technique. Amorphous behaviour of the sample has been verified by XRD study. FT-IR analysis confirmed the presence of various bonds in the host lattice.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2024
Jazan University, College of Science, Department of Physical Sciences, Physics Division, P.O. Box 114, 45142 Jazan, Saudi Arabia; Nanotechnology Research Unit, College of Science, Jazan University, P.O. Box. 114, Jazan 45142, Saudi Arabia. Electronic address:
In this study, an investigation was conducted on the structural and photoluminescence (PL) characteristics of LaAlBO (LAB) phosphors initially incorporated with Dy and Eu ions. Subsequently, the impact of varying Eu concentration while maintaining a constant Dy concentration was examined. Structural characterization was performed using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and energy-dispersive X-ray spectroscopy (EDS).
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2024
Department of Applied Physics, Delhi Technological University, Bawana Road, New Delhi 110042, India.
Barium lead alumino fluoroborate (BaPbAlFB) glasses singly and co-doped with Dy and Eu ions were prepared by melt quench method and studied their photoluminescence (PL) properties along with energy migration. Singly doped Dy/Eu ions in BaPbAlFB glasses under 365 and 393 nm excitation wavelengths emit the PL bands through Dy: (F → H and F → H) and Eu: (D→F) transitions located at (Dy: 483 and 575 nm) and (Eu: 613 nm) respectively. Further, tunability of PL emissions is achieved by exciting the Dy/Eu co-doped BaPbAlFB glasses at various wavelengths.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2024
Changchun Institute of Technology, Changchun, Jilin 130012, China.
A series of emission-tunable NaLuF:RE (RE = Dy, Tb, Eu, Tm) phosphors were firstly synthesized by a glycine assisted one-step hydrothermal process. The structure and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results revealed that the samples were NaLuF, LuF and NaLuF and the size and shape of the products could be tuned just by adjusting the pH values of the initial reaction solutions or by adjusting the RE/NaF ratio or RE/NaBF ratio.
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