The preparation of a number of alkyl and alkoxy derivatives of pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione derivatives utilising a cheap, practical, low energy, 'green', single-pass continuous flow photochemical reactor is reported. Their (1)H and (13)C NMR spectra are fully assigned, revealing some general characteristics not previously reported for this class of compound, which should aid the assignment and prediction of the NMR spectra of PCUD derivatives.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/mrc.3879 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Molecular Acrobatics in Polycyclic Frames: Synthesis of "Kurmanediol" via Post-synthetic Modification of Cage Molecules by Olefinic Metathesis.
J Org Chem
August 2023
Department of Chemistry, Institution Indian Institute of Technology, Powai, Mumbai 400076, India.
We report late-stage ring-opening metathesis (ROM), ring-rearrangement metathesis (RRM), and ring-closing metathesis (RCM) approaches to generate expanded pentacycloundecane (PCUD) cage derivatives. These higher-order intricate polycyclic cage systems are aesthetically pleasing and structurally intriguing. Their assembly maintains molecular symmetry during the entire synthetic sequence.
View Article and Find Full Text PDFPreparation and complete (1) H and (13)C assignment of some pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCUD) derivatives.
Magn Reson Chem
December 2012
Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK.
The preparation of a number of alkyl and alkoxy derivatives of pentacyclo[5.4.0.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!