Facile preparation of oriented nanoporous silica films from solvent-free liquid-crystalline mixtures.

Chem Commun (Camb)

Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan.

Published: November 2012

Mixtures of an amphiphilic perylene bisimide derivative and tetramethoxysilane in the absence of solvents have been found to exhibit stable columnar liquid-crystalline phases which transform into macroscopically oriented nanoporous silica films as a result of simple mechanical shearing.

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http://dx.doi.org/10.1039/c2cc36306bDOI Listing

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