We report the synthesis of two-dimensional (2D) dendritic Au nanowires (DNWs) with diameters of 100-200 nm in an aqueous solution of long-chain amidoamine derivative (C18AA), which acted as both capping and reducing agent, and the preparation of large 2D DNWs with diameters of 400-700 nm by seeded growth of the original DNWs. The seeded growth method in the presence of C18AA enables the fabrication of novel neuron-shaped Au nanostructures consisting of two DNWs dangling from both ends of an ultrathin Au nanowire.
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http://dx.doi.org/10.1021/la3033918 | DOI Listing |
Nat Commun
January 2025
Faculty of Materials Science and Energy Engineering, Shenzhen University of Advanced Technology, Shenzhen, China.
Aqueous zinc ion batteries exhibit great prospects due to their low cost and high safety, while their lifespan is limited by severe dendritic growth problems. Herein, we develop an anti-dendrite hot-pressing separator interlayer through a mass-producible hot-pressing strategy, by spreading metal-organic framework (MOF) precursor on nonwoven matrix followed by a simple hot-pressing process. The in situ modification of MOF crystals on fiber surface processes abundant nitrogenous functional groups and high specific surface area (190.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Materials Science and Engineering, Faculty of Mechanical Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherlands.
Rechargeable lithium-sulfur batteries (LiSBs) assembled with earth-abundant and safe Li anodes are less prone to form dendrites on the surface, and sulfur-containing cathodes offer considerable potential for achieving high energy densities. Nevertheless, suitable sulfur host materials and their interaction with electrolytes are at present key factors that retard the commercial introduction of these batteries. Here we propose a two-dimensional metallic carbon phosphorus framework, namely, 2D CP, as a promising sulfur host material for inhibiting the shuttle effect and improving electronic conductivity in high-performance Li-S batteries.
View Article and Find Full Text PDFMater Horiz
December 2024
School of Energy and Chemical Engineering, UNIST, Ulsan 44919, Korea.
A Zn-coordinated porphyrinic artificial solid-electrolyte interphase (αSEI) layer, named [Zn]PP-4COO-(Zn), was developed to improve the reversibility of zinc metal plating/stripping in aqueous zinc-ion batteries (ZIBs). Inspired by nitrogen-terminating sites of biological molecules coordinating and transporting zinc in zinc metabolic processes, the αSEI layer was designed with zinc ions connecting porphyrinic building blocks to form two-dimensional clathrate sheets and stacking -plane sheets along the -axis to allow N cages to align and form porphyrinic N channels for zinc transport. The [Zn]PP-4COO-(Zn) αSEI layer was Zn-conductive and structurally durable during repeated stripping/plating.
View Article and Find Full Text PDFInorg Chem
December 2024
Institute of Materials Research and Engineering (IMRE), Agency of Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, Republic of Singapore.
Two-dimensional (2D) metal-organic framework sheets, in comparison to the 3D analogues, offer potential advantages for intercalation of guest components between the layers, exfoliation/dispersion into solutions, and processing into thin films. As a versatile platform for leveraging organic functions, the 2D Zr(IV)-carboxylate net here features a dendritic Sierpinski tritopic linker with conjugated alkyne branches and a photoactive triphenylamine core. The 2D solid can be easily dispersed in water and many other solvents, resulting in stable and fluorescent suspension for sensing nitro aromatic compounds and Fe ions with high quenching efficiencies and ultralow limits of detection.
View Article and Find Full Text PDFHum Pathol
November 2024
Institute of Pathology, University Hospital Essen, University of Duisburg-Essen, Hufelandstr. 55, 45147 Essen, Germany. Electronic address:
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