Resonant X-ray emission spectroscopy reveals d-d ligand-field states involved in the self-assembly of a square-planar platinum complex.

Claudio Garino Erik Gallo Nikolay Smolentsev Pieter Glatzel Roberto Gobetto Carlo Lamberti Peter J Sadler Luca Salassa

Phys Chem Chem Phys

Department of Chemistry and NIS Centre of Excellence, University of Turin, Via P. Giuria 7, 10125 Turin, Italy.

Published: November 2012

Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2':6',2''-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy.

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http://dx.doi.org/10.1039/c2cp42451g	DOI Listing

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