We have investigated the energy loss of hot electrons in metallic graphene by means of GHz noise thermometry at liquid helium temperature. We observe the electronic temperature T ∝ V at low bias in agreement with the heat diffusion to the leads described by the Wiedemann-Franz law. We report on T ∝ √V behavior at high bias, which corresponds to a T(4) dependence of the cooling power. This is the signature of a 2D acoustic phonon cooling mechanism. From a heat equation analysis of the two regimes we extract accurate values of the electron-acoustic phonon coupling constant Σ in monolayer graphene. Our measurements point to an important effect of lattice disorder in the reduction of Σ, not yet considered by theory. Moreover, our study provides a strong and firm support to the rising field of graphene bolometric detectors.
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http://dx.doi.org/10.1103/PhysRevLett.109.056805 | DOI Listing |
J Phys Chem Lett
January 2025
Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, China.
Single-atom manipulation has emerged as an effective strategy for enhancing the photocatalytic efficiency. However, the mechanism of photogenerated carrier dynamics under single-atom modulation remains unclear. Combining first-principles calculations and non-adiabatic molecular dynamics simulations, we systematically studied carrier transfer and recombination in the oxygen reduction reaction of single-atom-doped CN systems.
View Article and Find Full Text PDFACS Nano
January 2025
Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos 13566-590, Brazil.
Monolayers of transition-metal dichalcogenides, such as MoS, have attracted significant attention for their exceptional electronic and optical properties, positioning them as ideal candidates for advanced optoelectronic applications. Despite their strong excitonic effects, the atomic-scale thickness of these materials limits their light absorption efficiency, necessitating innovative strategies to enhance light-matter interactions. Plasmonic nanostructures offer a promising solution to overcome those challenges by amplifying the electromagnetic field and also introducing other mechanisms, such as hot electron injection.
View Article and Find Full Text PDFBMC Chem
January 2025
Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, P.O. 13759, Cairo, Egypt.
In this work, selenium (IV) ions were adsorbed from aqueous solutions by the strongly basic anion exchange resin Amberlite IRA-400. The morphology of the resin before and after Se(IV) sorption was investigated using different techniques such as energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). To determine the ideal sorption conditions, a batch approach was used to examine the variables affecting Se(IV) sorption performance, including pH, shaking time, adsorbent dosage, initial metal ion concentration, and temperature.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Department of Chemistry, University of Ulsan, 93 Daehak-ro, Nam-gu, Ulsan 44610, South Korea.
Understanding plasmon damping in gold nanorods (AuNRs) is crucial for optimizing their use in photochemical processes and biosensing. This study used dark-field microscopy and spectroscopy to explore plasmon damping in single AuNRs on graphene monolayers (AuNR@GL) with pyridine derivatives as adsorbates. The Au-graphene heterostructure caused a Fermi-level downshift, making graphene a dominant electron acceptor.
View Article and Find Full Text PDFFood Res Int
January 2025
State Key Laboratory of Crop Stress Adaptation and Improvement, College of Agriculture, Henan University, Kaifeng 475004, China; Food Laboratory of Zhongyuan, Luohe 462300, China. Electronic address:
Hydrothermal treatment is a physical modification technology to alter starch structures for the production of resistant starch (RS). However, the underlying regulation mechanism of the multiscale structure and digestive properties of starch by dual hydrothermal synergistic treatment remains unclear. To solve this problem, A- and B-type wheat starch granules (AWS and BWS) were separated and subjected to toughening and heat-moisture synergistic treatment (THT) with various moisture content (10 %, 15 %, 20 %, 25 %).
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