We present de Haas-van Alphen and resistivity data on single crystals of the delafossite PdCoO(2). At 295 K we measure an in-plane resistivity of 2.6 μΩ cm, making PdCoO(2) the most conductive oxide known. The low-temperature in-plane resistivity has an activated rather than the usual T(5) temperature dependence, suggesting a gapping of effective scattering that is consistent with phonon drag. Below 10 K, the transport mean free path is ∼20 μm, approximately 10(5) lattice spacings and an astoundingly high value for flux-grown crystals. We discuss the origin of these properties in light of our data.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.109.116401 | DOI Listing |
Nat Commun
February 2024
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN, 55455, USA.
Despite their highly anisotropic complex-oxidic nature, certain delafossite compounds (e.g., PdCoO, PtCoO) are the most conductive oxides known, for reasons that remain poorly understood.
View Article and Find Full Text PDFNano Lett
August 2023
Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
Nano Lett
October 2021
Unité Mixte de Physique, CNRS, Thales, Université Paris Sud, Université Paris-Saclay, F-91767 Palaiseau, France.
Rashba interfaces yield efficient spin-charge interconversion and give rise to nonreciprocal transport phenomena. Here, we report magnetotransport experiments in few-nanometer-thick films of PdCoO, a delafossite oxide known to display a large Rashba splitting and surface ferromagnetism. By analyzing the angle dependence of the first- and second-harmonic longitudinal and transverse resistivities, we identify a Rashba-driven unidirectional magnetoresistance that competes with the anomalous Nernst effect below the Curie point.
View Article and Find Full Text PDFScience
June 2020
Laboratory of Quantum Materials (QMAT), Institute of Materials, École Polytechnique Fédéral de Lausanne (EPFL), 1015 Lausanne, Switzerland.
Microstructures can be carefully designed to reveal the quantum phase of the wave-like nature of electrons in a metal. Here, we report phase-coherent oscillations of out-of-plane magnetoresistance in the layered delafossites PdCoO and PtCoO The oscillation period is equivalent to that determined by the magnetic flux quantum, , threading an area defined by the atomic interlayer separation and the sample width, where is Planck's constant and is the charge of an electron. The phase of the electron wave function appears robust over length scales exceeding 10 micrometers and persisting up to temperatures of T > 50 kelvin.
View Article and Find Full Text PDFACS Energy Lett
September 2019
Max Planck Institute for Chemical Physics of Solids, 01187 Dresden, Germany.
The observation of extraordinarily high conductivity in delafossite-type PdCoO is of great current interest, and there is some evidence that electrons behave like a fluid when flowing in bulk crystals of PdCoO. Thus, this material is an ideal platform for the study of the electron transfer processes in heterogeneous reactions. Here, we report the use of bulk single-crystal PdCoO as a promising electrocatalyst for hydrogen evolution reactions (HERs).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!