The threading of bis(dialkylammonium) ions through the DB24C8-like openings of a molecular cage proceeds through a stepwise mechanism: formation of a face-to-face complex between the NH2(+) centers and the crown ether, significant dissociation of this complex, and passage of the terminus of the cation through the macrocycle.
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Observation of face-to-face host-guest associated states prior to threading of dialkylammonium ions into the DB24C8-like openings of a molecular cage.
Chem Commun (Camb)
May 2013
Department of Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, Taiwan, ROC.
The threading of bis(dialkylammonium) ions through the DB24C8-like openings of a molecular cage proceeds through a stepwise mechanism: formation of a face-to-face complex between the NH2(+) centers and the crown ether, significant dissociation of this complex, and passage of the terminus of the cation through the macrocycle.
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