Cationic ruthenium catalysts for alkyne annulations with oximes by C-H/N-O functionalizations.

J Org Chem

Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.

Published: October 2012

Cationic ruthenium(II) complexes enabled efficient redox-neutral annulations of alkynes with readily available oximes. The catalytic dehydrative C-H/N-O bond functionalization proved to be broadly applicable and was shown to proceed through a reversible cyclometalation.

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http://dx.doi.org/10.1021/jo301768bDOI Listing

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