cis-Dibromidobis(2-phenyl-pyridine-κN)platinum(II).

Acta Crystallogr Sect E Struct Rep Online

School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.

Published: September 2012

In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl-pyridine (ppy) ligands and two Br(-) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0 (3) and 47.3 (3)°. In the crystal, the complex mol-ecules are stacked in columns along the a axis. In the columns, there are numerous intra- and inter-molecular π-π inter-actions between the six-membered rings, the shortest ring centroid-centroid distance being 3.774 (6) Å.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435592PMC
http://dx.doi.org/10.1107/S160053681203471XDOI Listing

Publication Analysis

Top Keywords

ppy ligands
8
cis-dibromidobis2-phenyl-pyridine-κnplatinumii title
4
title complex
4
complex [ptbr2c11h9n2]
4
[ptbr2c11h9n2] ptii
4
ptii ion
4
ion distorted
4
distorted cis-br2n2
4
cis-br2n2 square-planar
4
square-planar coordination
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!