The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl-imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxyl-ate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°.
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http://dx.doi.org/10.1107/S160053681203111X | DOI Listing |
Sci Adv
March 2025
Tasmanian School of Medicine, College of Health and Medicine, University of Tasmania, 17 Liverpool Street, Hobart, Tasmania 7000, Australia.
Understanding plastics' harmful impacts on wildlife would benefit from the application of hypothesis agnostic testing commonly used in medical research to detect declines in population health. Adopting a data-driven, proteomic approach, we assessed changes in 745 proteins in a free-living nonmodel organism with differing levels of plastic exposure. Seabird chicks heavily affected by plastic ingestion demonstrated a range of negative health consequences: Intracellular components that should not be found in the blood were frequently detected, indicative of cell lysis.
View Article and Find Full Text PDFJ Neurol
March 2025
IRCCS Istituto Delle Scienze Neurologiche Di Bologna, Ospedale Bellaria, Via Altura 3, 40139, Bologna, Italy.
Background: Early stridor onset (≤ 3 years from disease onset) is a predictor of shorter survival in Multiple System Atrophy (MSA), but its role on disease progression is not yet established. In MSA, previous studies on trajectories of disease did not include stridor and REM sleep behavior disorder (RBD) as clinical variable. The aims of the study were: (1) to investigate disease progression in MSA patients with early stridor onset and with early stridor and/or RBD onset; (2) to assess cerebrospinal fluid (CSF) levels of neurofilament light chain protein (NfL) in MSA patients with early onset sleep disorders.
View Article and Find Full Text PDFBMC Vet Res
February 2025
College of Animal Science, Inner Mongolia Agricultural University, Hohhot, 010018, China.
Renowned for its invaluable undercoat, the cashmere goat is well known. The growth of cashmere fibre initiates when the relatively inactive telogen stage transitions to the anagen stage, which involves active proliferation. However, the molecular mechanisms responsible for this process are still unclear.
View Article and Find Full Text PDFEur J Paediatr Dent
March 2025
Italian Society of Paediatric Dentstry - Societa Italiana di Odontoiatria Infantile (SIOI).
Aim: The Italian Society of Paediatric Dentistry (SIOI) is committed to encourage all dental practitioners to provide safe and updated prevention and treatment strategies for oral diseases in paediatric patients. SIOI promotes quality communication and information to parents and caregivers for prevention and awareness of oral diseases in the paediatric population. The purpose of this SIOI Policy is to provide dental professionals with comprehensive guidance on paediatric restorative materials, ensuring that treatment decisions are based on the latest and highest-quality scientific evidence.
View Article and Find Full Text PDFInt J Biol Macromol
February 2025
Department of Environmental Engineering and Management, Chaoyang University of Technology, Taichung 413310, Taiwan. Electronic address:
In the present work, a novel pyrazole-basedchitosan Schiff base material was prepared using 5-(4-Methoxyphenoxy)-3-methyl-1-phenyl-1H-pyrazol-4-carboxaldehydeand was modified using MoS-CN, where the nanoparticles get embedded within the polymeric matrix. Further composite material was analyzed and characterized using various analytical techniques such as XRD, SEM, FTIR, EDS, BET and TGA. The adsorbent material was analyzed for the adsorptive take-up process with a metal ion concentration ranging from 20 to 100 mgL and the adsorption occurred due to the interaction between the metal ions and the chitosan Schiff base.
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