An analytical procedure was developed to determine the concentration of 25 impurities (Li, Be, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Mo, Ag, Cd, In, Sm, Eu, Gd, Dy, W, Pb, Bi and Th) in a uranium matrix using the quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS). The dissolution of U(3)O(8) powder was made with a mixture of hydrochloric acid and nitric acid. Then, a selective separation of uranium using the UTEVA column was used before measurement by Q-ICP-MS. The procedure developed was verified using the Certified Reference Material "Morille". The analytical results agree well except for 5 elements where values are underestimated (Li, Be, In, Pb and Bi). Among the list of impurities, iron was particularly investigated because it is well known that this element possesses a polyatomic interference that increases the detection limit. A comparison between iron detection limits obtained with different methods was performed. Iron polyatomic interference was at least reduced, or at best entirely resolved in some cases, by using the cold plasma or the collision/reaction cell with several gases (He, NH(3) and CH(4)). High-resolution ICP-MS was used to compare the results obtained. A detection limit as low as 8 ng L(-1) was achieved.
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http://dx.doi.org/10.1016/j.talanta.2012.05.041 | DOI Listing |
Sci Rep
October 2024
IT4Innovations and Nanotechnology Centre, CEET, VSB-Technical University of Ostrava, 17. listopadu 2172/15, 70800, Ostrava, Czech Republic.
Correlated band theory implemented as a combination of the relativistic density functional theory with exact diagonalization [DFT+U(ED)] of the Anderson impurity term with Coulomb repulsion U in the 5f shell is applied to the magnetic field polarized state of [Formula: see text]. We demonstrate that the DFT+U(ED) approach provides a good agreement with very recent x-ray absorbtion near edge structure (XANES) and x-ray magnetic circular dichroism (XMCD) experiments. The branching ratio for the [Formula: see text] edge transitions of uranium, and the valence spin-orbit interaction per hole were evaluated in a perfect agreement with the XANES.
View Article and Find Full Text PDFJ Chem Phys
October 2024
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, USA.
Ionic liquids (ILs) are a unique class of solvents with potential applications in advanced separation technologies relevant to the nuclear industry. ILs are salts with low melting points and a wide range of tunable physical properties, such as viscosity, hydrophobiciy, conductivity, and liquidus range. ILs have negligible vapor pressure, are often non-flammable, and can have high thermal stability and a wide electrochemical window, making them attractive for use in separations processes relevant to the nuclear industry.
View Article and Find Full Text PDFEnviron Sci Technol
August 2024
College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China.
Large quantities of uranium-containing radioactive wastewater are typically generated during nuclear fuel cycle processes. Despite significant efforts, efficient capture of migratable hexavalent uranium U(VI) is still a huge challenge due to its acidity, radioactivity, coexisting organics, and high impurity cation abundance in wastewater. Herein, we have fabricated all-polymer-based 0D/2D CN/CN homostructure hybrids with an S-scheme electronic configuration by coordinating the band engineering of semiconductors to enrich uranium species from the complex wastewater environment.
View Article and Find Full Text PDFACS Omega
April 2024
Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson Air Force Base, Ohio 45433, United States.
Fission products may interact with structural materials in various nuclear energy applications and cause their mechanical performance to deteriorate. Therefore, it is important to study the effects of different fission products on the mechanical properties of structural materials. In this work, nickel was chosen as a model structural material system and dilute amounts of uranium and fission product impurities X = (Tc, Te, Sb, Ce, Eu, and U) up to 4 at % were used.
View Article and Find Full Text PDFACS Omega
March 2024
Department of Nuclear Engineering, University of Utah, 110 Central Campus Dr., Suite 2000, Salt Lake City, Utah 84112, United States.
Within the front end of the nuclear fuel cycle, many processes impart forensic signatures. Oxygen-stable isotopes (δO values) of uranium-bearing materials have been theorized to provide the processing and geolocational signatures of interdicted materials. However, this signature has been minimally utilized due to a limited understanding of how oxygen isotopes are influenced during uranium processing.
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