We report the synthesis of pure and Mn doped ZnO in the form of nanosheets using a simple and single step procedure involving a microwave assisted chemical method. As prepared Mn-doped ZnO nanosheets were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), ultra violet-visible (UV-Vis), Raman spectroscopy and magnetization measurements. The structural studies using XRD and TEM revealed the absence of Mn-related secondary phases and showed that Mn-doped ZnO comprise a single phase nature with wurtzite structure. FESEM and TEM micrographs show that the average diameter of Mn-ZnO assembled nanosheets is about approximately 50 nm, and the length of a Mn-doped ZnO nanosheet building block which is made up of thin mutilayered sheets is around approximately 300 nm. Concerning the Raman scattering spectra, the shift in peak position of E2 (high) mode toward low frequencies due to the Mn doping could be explained well by means of the spatial correlation model. Magnetic measurements showed that Mn-doped ZnO nanosheets exhibit ferromagnetic ordering at or above room temperature.
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http://dx.doi.org/10.1166/jnn.2012.6248 | DOI Listing |
Beilstein J Nanotechnol
October 2024
Institute of Physical Chemistry ''Ilie Murgulescu'' of the Romanian Academy, 202 Splaiul Independentei, 060021 Bucharest, Romania.
Although the microwave-assisted sol-gel method is quite frequently used for the preparation of oxide nanostructures, the synergism of the reaction pathways is not fully explained. However, state-of-the-art theoretical and practical results of high novelty can be achieved by continuously evaluating the as-synthesized materials. The present paper presents a comparative study of Mn-doped ZnO nanopowders prepared by both sol-gel and microwave-assisted sol-gel methods.
View Article and Find Full Text PDFHeliyon
July 2024
Institute for Integrated Micro and Nano Systems, IMNS School of Engineering, University of Edinburgh, UK.
In this study, band structure and optical properties of Manganese (Mn) doped ZnO are investigated adopting first-principles study calculations. It is observed that, by addition of Mn in ZnO crystal, the electrical properties like conductivity and dielectric function of material have been improved. The elastic constants for the elements are also calculated which shows that the element is stable after addition of dopant.
View Article and Find Full Text PDFSci Rep
March 2024
Department of Medicinal Plants, Faculty of Agriculture and Natural Resources, Arak University, Arak, 38156-8-8349, Iran.
Biological and green synthesis of nanomaterial is a superior choice over chemical and physical methods due to nanoscale attributes implanted in a green chemistry matrix, have sparked a lot of interest for their potential uses in a variety of sectors. This research investigates the growing relevance of nanocomposites manufactured using ecologically friendly, green technologies. The transition to green synthesis correlates with the worldwide drive for environmentally sound procedures, limiting the use of traditional harsh synthetic techniques.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
April 2024
Multidisciplinary Research and Innovation Laboratory, Sultan Moulay Slimane University of Beni Mellal, FP Khouribga, BP.145, 2500, Khouribga, Morocco.
MnO/ZnO-AlO-CeO catalyst was synthesized through a solid-state process from a 3% Mn-doped Zn-(Al/Ce) layered double hydroxide structure. Detailed structural and optical characterization using XRD, FTIR, UV-visible DRS, and TEM was conducted. By investigating clofibric acid (CA) degradation in aqueous solution, MnO/ZnO-AlO-CeO photocatalytic activity was evaluated.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2024
School of Physics, University of Electronic Science and Technology of China, Chengdu, 610054, PR China. Electronic address:
The cycling stability of aqueous Zn-ion battery (AZIB) is a serious issue for their successful application, mainly due to the considerable growth of Zn dendrites and the existence of side effects during operation. Herein, the hierarchically three-dimensional (3D) fractal structure of the ZnO/Zn/CuO@Cu (ZZCC) anode is prepared by a two-step process, where CuO nanowires are prepared on Cu foam by thermal oxidation method and Zn layer and ZnO surface are formed by plating. This fractal structure increases the electrodynamic surfaces and reduces the local current density, which can regulate Zn plating and inhibit dendritic growth and side effects.
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