Synthesis of a Fe(II)SH complex stabilized by an intramolecular N-H···S hydrogen bond, which acts as a H2S donor.

Inorg Chem

Laboratoire de Chimie et Biochimie Pharmacologique et Toxicologique, UMR 8601 CNRS, Université Paris Descartes, PRES Paris cité, 45 rue des Saints Pères, 75270 Paris Cedex 06, France.

Published: October 2012

Through use of the reversible protonation of an iron(II) complex containing a deprotonated carboxamido moiety, we prepared and fully characterized the first hydrogen(sulfido)iron(II) complex stabilized by an intramolecular hydrogen bond, which acts as a H(2)S donor in solution.

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Source
http://dx.doi.org/10.1021/ic300952dDOI Listing

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