Intramolecular Diels-Alder reactions of cyclobutenone and larger cycloalkenones are described. High levels of endo addition attained from Lewis acid catalysis translate to trans hydrindene junctions upon fragmentation of the tricyclic adducts.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3464979 | PMC |
| http://dx.doi.org/10.1021/ja307708q | DOI Listing |
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