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Nickel-catalyzed Kumada reaction of tosylalkanes with Grignard reagents to produce alkenes and modified arylketones. | LitMetric
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Nickel-catalyzed Kumada reaction of tosylalkanes with Grignard reagents to produce alkenes and modified arylketones.

Ji-Cheng Wu Lu-Bing Gong Yuanzhi Xia Ren-Jie Song Ye-Xiang Xie Jin-Heng Li

Angew Chem Int Ed Engl

State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.

Published: September 2012

Open a new door: The first example of alkene synthesis from alkyl electrophiles with Grignard reagents using the Kumada cross-coupling reaction strategy is reported. This method opens a new door for the Kumada cross-coupling reaction, allowing alkenes to be prepared from the reaction of tosylalkanes with Grignard reagents.

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http://dx.doi.org/10.1002/anie.201205969DOI Listing

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