Highly selective and stable florescent sensor for Cd(II) based on poly (azomethine-urethane).

J Fluoresc

Department of Chemistry, Faculty of Sciences and Arts, Çanakkale Onsekiz Mart University, 17020 Çanakkale, Turkey.

Published: January 2013

In this study a kind of poly(azomethine-urethane); (E)-4-((2 hydroxyphenylimino) methyl)-2-methoxyphenyl 6-acetamidohexylcarbamate (HDI-co-3-DHB-2-AP) was prepared as in the literature and employed as a new fluorescent probe for detection of Cd(II) concentration. The photoluminescence (PL) measurements were carried out in the presence of several kinds of heavy metals. HDI-co-3-DHB-2-AP gave a linearly and highly stable response against Cd(II) as decreasing a new emission peak at 562 nm. Possible interferences of other ions were found too low. Detection limit of the sensor was found as 8.86 × 10(-4) mol L(-1). Resultantly, HDI-co-3- DHB-2-AP could be effectively used as an optical Cd(II) sensor.

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http://dx.doi.org/10.1007/s10895-012-1124-3DOI Listing

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