We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the F(12) schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the facilitation strength, one observes two distinct dynamical glass transition lines--continuous and discontinuous--merging at a dynamical tricritical-like point with critical decay exponents consistently related by MCT predictions. The mechanisms of dynamical arrest can be naturally interpreted in geometrical terms: the discontinuous and continuous transitions correspond to bootstrap and standard percolation processes, in which the incipient spanning cluster of frozen spins forms either a compact or a fractal structure, respectively. Our cooperative dynamical facilitation picture of glassy behavior is complementary to the one based on disordered systems and can account for higher-order singularity scenarios in the absence of a finite temperature thermodynamic glass transition. We briefly comment on the relevance of our results to finite spatial dimensions and to the F(13) schematic model.
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http://dx.doi.org/10.1063/1.4746695 | DOI Listing |
Dynamic transverse mode instability (TMI) has become one of the primary limitations for power scaling of high-power fiber lasers. Experimental evidence has shown that static mode degradation can suppress the dynamic TMI effect. This study reveals the physical mechanisms behind the mitigation of dynamic TMI in two-mode fiber lasers through static mode degradation.
View Article and Find Full Text PDFPhys Rev E
November 2024
Fachbereich Physik, Universität Konstanz, 78457 Konstanz, Germany.
This work presents a theoretical analysis of the motion of a tracer colloid driven by a time-dependent force through a viscoelastic fluid. The recoil of the colloid after application of a strong force is determined. It provides insights into the elastic forces stored locally in the fluid and their weakening by plastic processes.
View Article and Find Full Text PDFSoft Matter
January 2025
Tata Institute of Fundamental Research, Gopanpally Village, Hyderabad-500046, India.
The glass-like slow dynamics in confluent epithelial monolayers is crucial for wound healing, embryogenesis, cancer progression, Experiments have indicated several unusual properties in these systems. Unlike ordinary glasses, the glassiness in cellular systems strongly correlates with their static properties and is sub-Arrhenius. These results imply that the slow dynamics in epithelial monolayers is either not glassy or the underlying mechanism is different from ordinary glasses.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
Institut of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Germany.
Accurately calculated infrared spectra are essential for supporting experimental interpretation, yet full-space anharmonic vibrational structure calculations are only feasible for a limited number of degrees of freedom. Fortunately, characteristic spectroscopic signatures are often dominated by a few key vibrations. We propose a computational protocol specifically tailoring high dimensional anharmonic potential energy surfaces for the accurate and efficient calculation of such spectral signatures with vibrational coupled cluster response theory.
View Article and Find Full Text PDFJ Phys Chem B
December 2024
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States.
Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudocritical trace across all finite dimensions. This characteristic could serve as a crucial test for distinguishing between theories of glass formation. We here examine these critical fluctuations, as captured by the well-established non-Gaussian parameter, within both mode-coupling theory (MCT) and dynamical mean-field theory (DMFT) across dimensions for hard sphere fluids and for the minimally structured Mari-Kurchan model.
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