This article aims at an account of what is known about the potential for applications of quasicrystals and related compounds, the so-called family of Complex Metallic Alloys (CMAs‡). Attention is focused at aluminium-based CMAs, which comprise a large number of crystalline compounds and quasicrystals made of aluminium alloyed with transition metals (like Fe or Cu) or normal metals like Mg. Depending on composition, the structural complexity varies from a few atoms per unit cell up to thousands of atoms. Quasicrystals appear then as CMAs of ultimate complexity and exhibit a lattice that shows no periodicity anymore in the usual 3-dimensional space. Properties change dramatically with lattice complexity and turn the metal-type behaviour of simple Al-based crystals into a far more complex behaviour, with a fingerprint of semi-conductors that may be exploited in various applications, potential or realised. An account of the ones known to the author is given in the light of the relevant properties, namely light absorption, reduced adhesion and friction, heat insulation, reinforcement of composites for mechanical devices, and few more exotic ones. The role played by the search for applications of quasicrystals in the development of the field is briefly addressed in the concluding section.
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http://dx.doi.org/10.1039/c2cs35110b | DOI Listing |
Natl Sci Rev
December 2024
School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074, China.
Because of the lack of translational symmetry, calculating the energy spectrum of an incommensurate system has always been a theoretical challenge. Here, we propose a natural approach to generalize energy band theory to incommensurate systems without reliance on the commensurate approximation, thus providing a comprehensive energy spectrum theory of incommensurate systems. Except for a truncation-dependent weighting factor, the formulae of this theory are formally almost identical to that of Bloch electrons, making it particularly suitable for complex incommensurate structures.
View Article and Find Full Text PDFACS Nano
December 2024
Dipartimento di Fisica, Sapienza Università di Roma, P. le Aldo Moro 5, 00185 Rome, Italy.
One of the frontiers of nanotechnology is advancing beyond the periodic self-assembly of materials. Icosahedral quasicrystals, aperiodic in all directions, represent one of the most challenging targets that has yet to be experimentally realized at the colloidal scale. Previous attempts have required meticulous human-designed building blocks and often resulted in interactions beyond the current experimental capabilities.
View Article and Find Full Text PDFChem Rev
October 2024
International Institute for Nanotechnology, Northwestern University, Evanston, Illinois 60208, United States.
Programming the organization of discrete building blocks into periodic and quasi-periodic arrays is challenging. Methods for organizing materials are particularly important at the nanoscale, where the time required for organization processes is practically manageable in experiments, and the resulting structures are of interest for applications spanning catalysis, optics, and plasmonics. While the assembly of isotropic nanoscale objects has been extensively studied and described by empirical design rules, recent synthetic advances have allowed anisotropy to be programmed into macroscopic assemblies made from nanoscale building blocks, opening new opportunities to engineer periodic materials and even quasicrystals with unnatural properties.
View Article and Find Full Text PDFLight Sci Appl
September 2024
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, China.
Quasicrystal metasurfaces, a kind of two-dimensional artificial optical materials with subwavelength meta-atoms arranged in quasi-periodic tiling schemes, have attracted extensive attentions due to their novel optical properties. In a recent work, a dual-functional quasicrystal metasurface, which can be used to simultaneously generate the diffraction pattern and holographic image, is experimentally demonstrated. The proposed method expands the manipulation dimensions for multi-functional quasicrystal metasurfaces and may have important applications in microscopy, optical information processing, optical encryption, etc.
View Article and Find Full Text PDFPhys Rev E
June 2024
Department of Physics, Zhejiang Normal University, Jinhua 321004, People's Republic of China.
The understanding of quantum phase transitions in disordered or quasicrystal media is a central issue in condensed matter physics. In this paper we investigate localization properties of the two-dimensional Aubry-André model. We find that the system exhibits self-duality for the transformation between position and momentum spaces at a critical quasiperiodic potential, leading to an energy-independent Anderson transition.
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