A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 143

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

A PHP Error was encountered

Severity: Warning

Message: Attempt to read property "Count" on bool

Filename: helpers/my_audit_helper.php

Line Number: 3100

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler

File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Self-assembly of isomeric clamshell dimers of platinum(II). | LitMetric

Self-assembly of isomeric clamshell dimers of platinum(II).

Dalton Trans

Department of Chemistry, University of Western Ontario, London, Canada N6A 5B7.

Published: October 2012

AI Article Synopsis

  • - The study focuses on the controlled synthesis of specific isomeric organoplatinum compounds known as clamshell dimers, created from simpler mononuclear precursors using self-assembly techniques.
  • - The synthesis takes advantage of the slow isomerization processes at platinum(II), resulting in different isomers depending on the reactants and conditions, leading to mixtures that can transform into more stable forms.
  • - The research confirms the structures of these synthesized dimers, analyzes the equilibria of the chemical reactions involved, and utilizes DFT calculations for deeper understanding.

Article Abstract

The controlled synthesis of isomeric organoplatinum clamshell dimers [Pt(2)Me(2)(μ(2)-κ(3)-6-dppd)(2)](2+), 6-dppd = 1,4-di-2-pyridyl-5,6,7,8,9,10-hexahydrocycloocta[d]pyridazine, is reported. The new complexes are formed selectively by self-assembly from mononuclear precursors, taking advantage of the slow cis-trans isomerization at platinum(II). Thus reaction of endo-[PtClMe(κ(2)-6-dppd)] with AgOTf gave endo,endo-[Pt(2)Me(2)(μ(2)-κ(3)-6-dppd)(2)](2+), while the reaction of [PtMe(2)(κ(2)-6-dppd)] with HOTf in solvent S = Me(2)C=O or MeCN gave first a mixture of exo- and endo-[PtMe(S)(κ(2)-6-dppd)](+) and then, by loss of solvent, a mixture of exo,exo- and endo,endo-[Pt(2)Me(2)(μ(2)-κ(3)-6-dppd)(2)](2+). The endo,endo isomer slowly isomerized to the more stable exo,exo isomer in solution. Reaction of PPh(3) with endo-[PtClMe(κ(2)-6-dppd)] gave a mixture of endo- and exo-[PtMe(PPh(3))(κ(2)-6-dppd)](+) but reaction with exo,exo-[Pt(2)Me(2)(μ(2)-κ(3)-6-dppd)(2)](2+) gave exo-[PtMe(PPh(3))(κ(2)-6-dppd)](+) selectively, with retention of stereochemistry. The structures of the clamshell dimers and of key precursors are reported and equilibria are studied both experimentally and by DFT calculations.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c2dt31584jDOI Listing

Publication Analysis

Top Keywords

clamshell dimers
12
self-assembly isomeric
4
isomeric clamshell
4
dimers platinumii
4
platinumii controlled
4
controlled synthesis
4
synthesis isomeric
4
isomeric organoplatinum
4
organoplatinum clamshell
4
dimers [pt2me2μ2-κ3-6-dppd2]2+
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!