The shape controlled synthesis of high quality colloidal lead selenide (PbSe) nanocrystals (NCs) was achieved through a simple solvothermal process. By using oleic acid (OA) as a ligand and activating agent for the Pb precursor, the evolution of the NCs from nanospheres to nanoflowers and finally to nanocubes was achieved by increasing the reaction time. Further, the shape variation from nanospheres to polyhedrons was readily realized through the increase of OA concentration in the stock solution. More interestingly, the change of the anion ligand was proven to be a facile method to control the structure and size of the nanoflowers. The X-ray diffraction and TEM analysis demonstrated the cubic rock salt structure of the synthesized PbSe NCs. Accompanied by comprehensive analytics, the discussion on the possible mechanisms for the shape evolution was provided.
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http://dx.doi.org/10.1039/c2dt30962a | DOI Listing |
J Am Chem Soc
November 2024
School of Materials Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, India.
Lead halide perovskite and chalcogenide heterostructures which share the ionic and covalent interface bonding may be the possible materials in bringing phase stability to these emerging perovskite nanocrystals. However, in spite of significant successes in the development of halide perovskite nanocrystals, their epitaxial heterostructures with appropriate chalcogenide nanomaterials have largely remained unexplored. Keeping the importance of these materials in mind, herein, epitaxial nanocrystal heterostructures of CsPbBr-PbSe are reported.
View Article and Find Full Text PDFChem Commun (Camb)
June 2024
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
To circumvent the issue of halide ion exchange in perovskites, we have decorated CsPbBr and CsPbI nanocrystals with different sized PbSe nanoparticles and demonstrated that it effectively prevents anion exchange reaction in CsPbBr/CsPbI nanoheterostructures (NHSs) as a consequence of halide vacancy passivation by the more covalent selenide anion.
View Article and Find Full Text PDFNano Lett
April 2024
MIIT Key Laboratory for Low-Dimensional Quantum Structure and Devices, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, 100081, P. R. China.
Nanomaterials (Basel)
September 2023
Sección de Electrónica del Estado Sólido, Departamento de Ingeniería Eléctrica, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Av. IPN 2508, Ciudad de México 07360, Mexico.
This work describes the spray pyrolysis deposition of PbSe films, using as-prepared PbSe colloids as the starting solution. The PbSe colloids were prepared by using the alkahest approach, where Pb and Se precursors were made to react with the following green polyols: glycerin, ethylene glycol, and propylene glycol, to subsequently spray them onto glass substrates. The results of the characterization indicated that amine or thiol groups-free and single-phase rock-salt cubic PbSe powder was obtained, producing nanocrystals 16-30 nm in size.
View Article and Find Full Text PDFChem Commun (Camb)
September 2023
Chinese Academy of Science (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Centre for Nanoscience and Technology, Beijing, 100190, China.
We report the 1D linear, 2D square, 2D honeycomb, and 3D topo-epitaxy long-range superstructures of oriented attached PbSe NCs. In particular, we discovered novel 1D linear and 3D superstructures, which implied different formation mechanisms compared with the PbSe superstructures previously reported. Our study not only demonstrates stronger design capability for oriented-attached PbSe superstructures, but also reveals important information about the interfacial behavior of the PbSe NCs during the self-assembly.
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