Ruthenium(III) chloride hydrate is a convenient catalyst for the addition of active methylene compounds to aryl alkynes. These reactions are rapid, operationally simple, and high yielding in cases. Most significantly, no precautions are required to exclude air or water from the reactions. All reagents are commercially available at reasonable prices, and the reactions can be conducted in disposable glassware with minimal solvent.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3423983 | PMC |
| http://dx.doi.org/10.1016/j.jorganchem.2012.05.017 | DOI Listing |
Publication Analysis
Top Keywords
ruthenium-catalyzed coupling
4
coupling alkynes
4
alkynes 13-diketones
4
13-diketones rutheniumiii
4
rutheniumiii chloride
4
chloride hydrate
4
hydrate convenient
4
convenient catalyst
4
catalyst addition
4
addition active
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!