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Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex. | LitMetric
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Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex.

Liang-An Chen Jiajia Ma Mehmet Ali Celik Hong-Lang Yu Zexing Cao Gernot Frenking Lei Gong Eric Meggers

Chem Asian J

College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, PR China.

Published: November 2012

Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration Λ or Δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

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 Source
http://dx.doi.org/10.1002/asia.201200532DOI Listing

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