A polyhedron-based metal-organic framework has been designed and constructed with a reo-e net, which is constructed from trinuclear nickel clusters and mixed ligands (copolymerization pattern). It comprises three kinds of polyhedra, which are the hexahedron, cuboctahedron and rhombicuboctahedron.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c2dt31122d | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Three Polyhedron-Based Metal-Organic Frameworks Exhibiting Excellent Acetylene Selective Adsorption.
ACS Appl Mater Interfaces
August 2024
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Materials Sciences, Zhejiang Normal University, Jinhua 321004, P.R. China.
The separation of acetylene (CH) from ethylene (CH) and ethane (CH) is crucial for the production of high-purity CH and the recovery of other gases. Polyhedron-based metal-organic frameworks (PMOFs) are characterized by their spacious cavities, which facilitate gas trapping, and cage windows with varying sizes that enable gas screening. In this study, we carefully selected a class of PMOFs based on V-type tetracarboxylic acid linker ( containing benzene ring, containing urea group and recombinant reconstructed on the basis of ) to study the relationship between pore environment and C adsorption and separation performance.
View Article and Find Full Text PDFDirect Separation of UO by Coordination Sieve Effect via Spherical Coordination Traps.
Small
June 2023
School of Chemistry, Biology, and Materials Science, East China University of Technology, Nanchang, 330013, China.
Molecule sieve effect (MSE) can enable direct separation of target, thus overcoming two major scientific and industrial separation problems in traditional separation, coadsorption, and desorption. Inspired by this, herein, the concept of coordination sieve effect (CSE) for direct separation of UO , different from the previously established two-step separation method, adsorption plus desorption is reported. The used adsorbent, polyhedron-based hydrogen-bond framework (P-HOF-1), made from a metal-organic framework (MOF) precursor through a two-step postmodification approach, afforded high uptake capacity (close to theoretical value) towards monovalent Cs , divalent Sr , trivalent Eu , and tetravalent Th ions, but completely excluded UO ion, suggesting excellent CSE.
View Article and Find Full Text PDFFrom a Metal-Organic Square to a Robust and Regenerable Supramolecular Self-assembly for Methane Purification.
Angew Chem Int Ed Engl
November 2022
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Porous supramolecular assemblies constructed by noncovalent interactions are promising for adsorptive purification of methane because of their easy regeneration. However, the poor stability arising from the weak noncovalent interactions has obstructed their practical applications. Here, we report a robust and easily regenerated polyhedron-based cationic framework assembled from a metal-organic square.
View Article and Find Full Text PDFFace-Sharing Archimedean Solids Stacking for the Construction of Mixed-Ligand Metal-Organic Frameworks.
J Am Chem Soc
September 2019
Department of Chemistry , Texas A&M University , College Station, Texas 77843-3255 , United States.
Reticular chemistry has been an important guiding principle for the design of metal-organic frameworks (MOFs). This approach utilizes discrete building units (molecules and clusters) that are connected through strong bonds into extended networks assisted by topological considerations. Although the simple design principle of connecting points and lines has proved successful, new design strategies are still needed to further explore the structures and functions of MOFs.
View Article and Find Full Text PDFA novel polyhedron-based metal-organic framework with high performance for gas uptake and light hydrocarbon separation.
Dalton Trans
April 2018
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
A novel polyhedron-based metal-organic framework [(CH3)2NH2]2[Zn3(TADIPA)2(DMF)2]·4DMF (JLU-Liu40), which possesses three types of cages with different shapes and sizes, has been successfully synthesized. The framework of JLU-Liu40 is constructed by two inorganic secondary building units (SBUs) of 4-connected square binuclear Zn-paddlewheel and 4-connected tetrahedron mononuclear Zn unit and one organic SBU, which has abundant Lewis basic sites (LBSs), and the framework can be simplified as a pair of 3-connected triangle geometries. Moreover, JLU-Liu40 shows a new (3, 4, 4)-connected topology with the Schläfli symbol {72, 9}2{74, 82}.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!