Magnetic anisotropy and magnetization dynamics of rare earth Gd atoms and dimers on Pt(111) and Cu(111) were investigated with inelastic tunneling spectroscopy. The spin excitation spectra reveal that giant magnetic anisotropies and lifetimes of the excited states of Gd are nearly independent of the supporting surfaces and the cluster size. In combination with theoretical calculations, we argue that the observed features are caused by strongly localized character of 4f electrons in Gd atoms and clusters.
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NanoImpact
December 2024
Biology Department & CESAM, University of Aveiro, 3810-193 Aveiro, Portugal. Electronic address:
Considering the increase in demand for rare earth elements (REEs) and their accumulation in soil ecosystems, it is crucial to understand their toxicity. However, the impact of lanthanum, yttrium and cerium oxides (LaO, YO and CeO, respectively) on soil organisms remains insufficiently studied. This study aims to unravel the effects of LaO, YO and CeO nanoparticles (NPs) and their corresponding bulk forms (0, 156, 313, 625, 1250 and 2500 mg/kg) on the terrestrial species Enchytraeus crypticus.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Magnetocaloric high-entropy alloys (HEAs) have recently garnered significant interest owing to their potential applications in magnetic refrigeration, offering a wide working temperature range and large refrigerant capacity. In this study, we thoroughly investigated the structural, magnetic, and magnetocaloric properties of equiatomic GdDyHoErTm HEAs. The as-cast alloy exhibits a single hexagonal phase, a randomly distributed grain orientation, and complex magnetism.
View Article and Find Full Text PDFBMC Microbiol
December 2024
School of Environment and Resource, Xichang University, Xichang, 615000, China.
The extensive mining of bastnasite (CeFCO) has caused pollution of lanthanum (La), cerium (Ce), and fuorine (F) in the surrounding farmland soil, severely threatening the safety of the soil ecosystem. However, the interaction effects of various chemical fractions of La, Ce, and F on the composition of microbial communities are unclear. In our study, high-throughput sequencing was performed based on the pot experiments of four types of combined pollution soils, i.
View Article and Find Full Text PDFEnviron Int
December 2024
Faculty of Health, University of Canterbury, Christchurch, New Zealand; GeoHealth Laboratory, University of Canterbury, Christchurch, New Zealand; College of Health, Wellbeing and Life Science, Sheffield Hallam University, Sheffield, United Kingdom.
Background: The beneficial impacts of greenspace availability on mental health are well-documented. However, longitudinal evidence using a spatial lifecourse perspective is rare, leaving the dynamics of how greenspace influences mental health across the lifecourse unclear. This study first uses prospective birth cohort data to examine the associations between greenspace availability in childhood (0-16 years) and mental health in adolescence (16 years) and between greenspace availability and mental health across adulthood (18-40 years).
View Article and Find Full Text PDFInorg Chem
December 2024
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.
The interplay between quantum effects from magnetic frustration, low-dimensionality, spin-orbit coupling, and crystal electric field in rare-earth materials leads to nontrivial ground states with unusual magnetic excitations. Here, we investigate YbTaO, which hosts a buckled square net of Yb ions with = 1/2 moments. The observed Curie-Weiss temperature is about -1 K, implying an antiferromagnetic coupling between the Yb moments.
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