AI Article Synopsis
- - The compound C(19)H(16)ClNO has a dihedral angle of 61.90° between its naphthalene and chloro-benzene rings, indicating some twisting in its structure.
- - A torsion angle of 174.6° suggests the arrangement of atoms around the C-N bonds is almost linear, which can influence molecular interactions.
- - The stability of the molecular structure is supported by an internal C-H⋯N hydrogen bond and is further enhanced by π-π stacking interactions in the crystal, with specific centroid-centroid distances noted.
Article Abstract
In the title compound, C(19)H(16)ClNO, the dihedral angle between the naphthalene ring system and the chloro-benzene ring is 61.90 (10)° and the C-N-C-C torsion angle is 174.6 (2)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯N hydrogen bond. The crystal structure features π-π stacking inter-actions [centroid-centroid distances = 3.7325 (17) and 3.8150 (17) Å].
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414968 | PMC |
| http://dx.doi.org/10.1107/S1600536812032114 | DOI Listing |
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