3,6-Diaza-octane-1,8-diaminium diiodide.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Pretoria, Private Bag X20, Hatfield 0028, South Africa.

Published: August 2012

The asymmetric unit of the title salt, C(6)H(20)N(4) (2+)·2I(-), comprises half a 3,6-diaza-octane-1,8-diaminium dication plus an I(-) anion. The dications are symmetrical and lie across crystallographic centres of inversion. In the crystal, the ions form a network involving mainly weak N-H⋯I inter-molecular inter-actions: two H atoms of the ammonium group form inter-actions with two I(-) anions and the H atom of the secondary amine forms a weak inter-action with a third I(-) cation. The third ammonium H atom is hydrogen bonded to a secondary amine of an adjacent cation. The backbone of the cation does not form a uniformly trans chain, but is 'kinked' [C-N-C-C torsion angle = 71.5 (2)°], probably to accommodate the direct hydrogen bond between the ammonium group and the secondary amine in an adjacent cation.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414312PMC
http://dx.doi.org/10.1107/S1600536812030127DOI Listing

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