In the title compound, C(20)H(22)O(5), the tetra-hydro-pyran, cyclo-hexene and cyclo-hexane rings of the xanthene ring system adopt half-chair, half-boat and chair conformations, respectively. The mean plane of the four roughly planar atoms of the tetra-hydro-pyran ring (r.m.s. deviation = 0.111 Å) forms a dihedral angle of 82.91 (4)° with the meth-oxy-benzene group. In the crystal, mol-ecules are linked via O-H⋯O and C-H⋯O hydrogen bonds into sheets lying parallel to the ac plane. The crystal is further consolidated by weak C-H⋯π inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414299PMC
http://dx.doi.org/10.1107/S160053681203005XDOI Listing

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