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(R(P))-5-Methyl-2-(propan-2-yl)cyclo-hexyl phen-yl{phen-yl[(1-phenyl-eth-yl)amino]-meth-yl}phosphinate. | LitMetric

(R(P))-5-Methyl-2-(propan-2-yl)cyclo-hexyl phen-yl{phen-yl[(1-phenyl-eth-yl)amino]-meth-yl}phosphinate.

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Published: August 2012

AI Article Synopsis

Article Abstract

In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra-hedral stereochemistry [bond-angle range about P = 103.33 (6)-115.24 (15)°] and has R(P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings are 40.4 (3) and 12.2 (2)°. In the crystal, a C-H⋯O inter-action links mol-ecules into chains which extend along [100].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414267PMC
http://dx.doi.org/10.1107/S1600536812028243DOI Listing

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There are two independent mol-ecules in the asymmetric unit of the title compound, C(19)H(33)N(2)O(4)P. In the crystal, the two independent mol-ecules are linked via N-H⋯O=P hydrogen bonds, forming dimers.

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