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cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))ethanamine-κN]palladium(II) dichloro-methane monosolvate. | LitMetric

cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))ethanamine-κN]palladium(II) dichloro-methane monosolvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

Published: August 2012

In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414152PMC
http://dx.doi.org/10.1107/S1600536812032308DOI Listing

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