In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-H⋯O, N-H⋯O and N-H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π-π inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [centroid-centroid distances = 3.592 (3) and 3.735 (3) Å].
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103 | PMC |
| http://dx.doi.org/10.1107/S1600536812029728 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Aquachloridobis[2-(1,3-thia-zol-4-yl-κN)-1H-benzimidazole-κN(3)]nickel(II) nitrate.
Acta Crystallogr Sect E Struct Rep Online
August 2012
Department of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.
In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-H⋯O, N-H⋯O and N-H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π-π inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [centroid-centroid distances = 3.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!