AI Article Synopsis
- The compound features a morpholine ring in a chair conformation as part of the morpholine-4-carbodithio-ate anion.
- The potassium ion is coordinated by eight atoms (four sulfur and four oxygen) in a unique bipyramidal arrangement.
- The structure consists of infinite two-dimensional networks in parallel layers, connected by hydrogen bonds, resulting in a three-dimensional arrangement.
Article Abstract
In the ionic title compound, K(+)·C(5)H(8)NOS(2) (-)·H(2)O, the morpholine ring of the morpholine-4-carbodithio-ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O-H⋯S hydrogen bonds, forming a three-dimensional structure.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100 | PMC |
| http://dx.doi.org/10.1107/S1600536812029613 | DOI Listing |
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