Nucleophilic oxidant: The reaction between a thiolato iron(II) complex 1 and superoxide in aprotic solvent at -90 °C yields a novel thiolato iron(III) peroxide intermediate 2, which exhibits unusually high nucleophilic reactivity. Compound 2 is an isomer of the thiolato iron(II) superoxide intermediate that is invoked in the reaction between superoxide reductase and superoxide.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3448492 | PMC |
| http://dx.doi.org/10.1002/anie.201203602 | DOI Listing |
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