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A nitroolefin functionalized BODIPY chemodosimeter for biothiols driven by an unexpected conjugated addition mechanism. | LitMetric
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A nitroolefin functionalized BODIPY chemodosimeter for biothiols driven by an unexpected conjugated addition mechanism.

Min Zhang Yangchun Wu Shengzhou Zhang Hongnian Zhu Qiong Wu Lijuan Jiao Erhong Hao

Chem Commun (Camb)

Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, China 241000.

Published: September 2012

A weakly fluorescent nitroolefin functionalized BODIPY 1 was prepared and rapidly reacted with thiols through an unexpected conjugated addition to the azafulvene ring of BODIPY to generate highly fluorescent BODIPYs 4 and 5. This reaction was applied for the highly selective and sensitive detection of Cys in living cells.

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 Source
http://dx.doi.org/10.1039/c2cc33749eDOI Listing

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