Solid-state and powder properties of softwood lignin and cellulose prepared by a new catalytic oxidation and acid precipitation method were characterized and compared with the commercial softwood and hardwood lignin and cellulose products. Catalytic pre-treated softwood lignin (CPSL) and cellulose (CPSC) were isolated from pine wood (Pinus sylvestris). CPSL with nearly micronized-scale particle size showed excellent powder flow and densification behavior due to the round shape and electrically minimum charged surface characteristics of particles. CPSL and the reference lignin studied were amorphous solids while CPSC exhibited a typical crystal lattice for cellulose I. In conclusion, physicochemical material properties of lignin and cellulose can be modified for biomedical and pharmaceutical applications with the present catalytic oxidation and acid precipitation method.
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http://dx.doi.org/10.1016/j.ijbiomac.2012.07.024 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Saha's Spectroscopy Laboratory, Department of Physics, University of Allahabad, Prayagraj, India.
The present study demonstrates the applicability of non-destructive and rapid spectroscopic techniques, specifically laser-induced fluorescence, ultraviolet-visible, and confocal micro-Raman spectroscopy, as non-invasive, eco-friendly, and robust multi-compound analytical methods for assessing biochemical changes in maize seedling leaves resulting from the treatment of aluminium oxide nanoparticles. The recorded fluorescence spectrum of the leaves shows that the treatment of different concentration of aluminium oxide nanoparticles decreases the chlorophyll content as observed by the increase in fluorescence emission intensity ratio (FIR = I/I). The analysis of ultraviolet-visible absorption measurements reveals that the amount of chlorophyll a, chlorophyll b, total chlorophyll and carotenoid decrease for treated plants with respect to untreated seedlings.
View Article and Find Full Text PDFJ Environ Manage
December 2024
Engineering Research Center of Agricultural Microbiology Technology, Ministry of Education & Heilongjiang Provincial Key Laboratory of Plant Genetic Engineering and Biological Fermentation Engineering for Cold Region & Key Laboratory of Microbiology, College of Heilongjiang Province & School of Life Sciences, Heilongjiang University, Harbin, 150080, China. Electronic address:
Improving lignocellulose degradation and organic matter conversion in agricultural and livestock wastes remains a great challenge. Here, the contribution of humic acid (HA) to lignocellulose degradation was investigated, focusing on the abundance of key microbial species and carbohydrate-active enzymes during aerobic composting. The results demonstrated that the addition of HA not only increased the complexity of the microbial network, but also enhanced the positive interaction between microorganism.
View Article and Find Full Text PDFMicrob Cell Fact
December 2024
College of Veterinary Medicine, Jilin Agricultural University, Changchun, 130118, China.
17β-estradiol (E2) is an endocrine disruptor, and even trace concentrations (ng/L) of environmental estrogen can interfere with the endocrine system of organisms. Lignin holds promise in enhancing the microbial degradation E2. However, the mechanisms by which lignin facilitates this process remain unclear, which is crucial for understanding complex environmental biodegradation in nature.
View Article and Find Full Text PDFSci Rep
December 2024
Faculty of Chemical Engineering, Urmia University of Technology, Urmia, 17165‑57166, Iran.
In this research, 3-(trimethoxysilyl)propyl methacrylate (MPS) silane agent was applied to modify the extracted wheat straw (WS) cellulose as a natural biopolymer. Polyacrylonitrile (PAN) was attached to the MPS-modified WS (MPS-WS) via in-situ polymerization to form PAN-WS biocomposite. AO-WS amidoximated biocomposite adsorbent was synthesized through amidoxime reaction and the effects of different parameters including agitation speed, metal ion concentration, and adsorbent dosage on its efficiency of Pb(II) removal were investigated using the Taguchi experimental design method.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Agricultural Engineering, College of Engineering, China Agricultural University, Beijing 100083, China.
This study aims to explore the redispersibility of dehydrated nanocellulose with p-toluenesulfonic acid (p-TsOH) fractionated lignin as an eco-friendly and cost-effective capping agent, to cope with the challenge of irreversible agglomeration and thus loss of nanoscale of nanocellulose upon dehydration. The intermixing of nanocellulose and p-TsOH fractionated lignin was achieved using an aqueous ethanol solution as the medium and films of lignin-blending cellulose nanofibers (L + CNF) with excellent redispersing properties were obtained after facile air-drying. With 0.
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