Cycles everywhere: The selectivity in the transformations of 1,3-diones to carbocycles by palladium-catalyzed bisallylic alkylations is strongly dependent on the phosphine that is employed. Moreover, synthesized vinylcyclopentenes can be easily transformed into cycloheptadiene derivatives through a carbon-carbon allylic bond cleavage.
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| http://dx.doi.org/10.1002/anie.201204629 | DOI Listing |
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