While numerous cases of immediate-type occupational asthma due to persulfates with positive skin prick test reactions to ammonium persulfate are well documented, few non-immediate type reactions have been described in the literature. We report the case of an atopic worker who developed work-related asthmatic symptoms shortly after he began his job in persulfate production. The diagnosis of asthma was corroborated by methacholine testing. The patient showed a positive patch test reaction to ammonium persulfate, while skin prick test was negative. He presented an isolated late symptomatic airway obstruction after a cumulative dose of 0.6 mg ammonium persulfate administered by a dosimeter method. An immunologic mechanism was demonstrated by a significant increase in exhaled nitric oxide and the number of eosinophils in induced sputum. These findings suggest that isolated late bronchial reactions to persulfates are mediated by eosinophilic inflammatory responses.
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http://dx.doi.org/10.1007/978-94-007-4546-9_10 | DOI Listing |
Sci Rep
January 2025
Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, University of Science and Technology, 16846-13114, Tehran, Iran.
In this research, graphene oxide-polyaniline (GO-PANI) nanocomposite was successfully synthesized and its catalytic performance was evaluated for the synthesis of N-aryl-1,4-dihydropyridine (1,4-DHP) and hydroquinoline derivatives. The GO nanosheets were prepared using the Hummers' method, and in-situ polymerization of aniline was conducted with ammonium persulfate (APS) serving as the polymerization initiator. The synthesized nanocomposite demonstrated notable efficiency, achieving yields of 80-94% for 1,4-DHP derivatives and 84-96% for hydroquinoline derivatives.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Laboratory of New Textile Materials and Advanced Processing Technologies, School of Textile Science and Engineering, Wuhan Textile University, Wuhan 430200, China. Electronic address:
Conductive hydrogel has drawn great concern in wearable sensors, human-machine interfaces, artificial intelligence (AI), health monitoring, et al. But it still remains challenge to develop hydrogel through facile and sustainable methods. In this work, a conductive, flexible, bendable and self-healing hydrogel (PBCM) composed of polyvinyl alcohol (PVA), borax, cellulose microfibers (CMFs) and MXene nanosheets was fabricated by a simple and efficient strategy.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Departamento de Química, Facultad de Ciencias Naturales, Matemáticas y Medio Ambiente, Universidad Tecnológica Metropolitana (UTEM), J. P. Alessandri 1242, Santiago 7800002, Chile.
A series of hydrophilic copolymers were prepared using 2-hydroxyethyl methacrylate (HEMA) and itaconic acid (IA) from free radical polymerization at different feed monomer ratios using ammonium persulfate (APS) initiators in water at 70 °C. The herbicide 2,4-dichlorophenoxy acetic acid (2,4-D) was grafted to Poly(HEMA--IA) by a condensation reaction. The hydrolysis of the polymeric release system, Poly(HEMA--IA)-2,4-D, demonstrated that the release of the herbicide in an aqueous phase depends on the polymeric system's pH value and hydrophilic character.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
School of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, PR China. Electronic address:
The high thermal stability and chemical durability of amide-linked covalent organic frameworks (amide COFs) make them a promising material for a range of new applications. Nevertheless, the low reversibility of the amide bond presents a significant challenge to the direct synthesis of amide-bonded COFs. In this paper, we present a simple method for synthesizing amide COFs.
View Article and Find Full Text PDFGels
December 2024
College of Resources and Environment Sciences, Gansu Agricultural University, Lanzhou 730070, China.
Under the increasing severity of drought issues and the urgent need for the resourceful utilization of agricultural waste, this study aimed to compare the soil water retention properties of hydrogels prepared from Chinese cabbage waste (CW) and banana peel (BP) using grafting techniques with acrylic acid (AA) and acrylamide (AAm). Free radical polymerization was initiated with ammonium persulfate (APS), and N, N'-methylene bisacrylamide (MBA) served as the crosslinking agent to fabricate the grafted polymer hydrogels. The hydrogels were subjected to detailed evaluations of their water absorption, reusability, and water retention capabilities through indoor experiments.
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